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704 and 0.857, respectively. The test-retest reliability of the sub- and total scores of the Y-SBT yielded an ICC of 0.82 (95% CI 0.74 - 0.87) and 0.89 (95% CI 0.84 - 0.93), respectively. The divergent validity for sub- and total-scores of the Y-SBT based on Quadruple Visual Analogue Scale score for on-going pain was r = 0.374 (p = 0.001) and r = 0.432 (p = 0.001), respectively. The Y-SBT had no ceiling or floor effects.The sub- and total Cronbach's α score for Y-SBT was 0.704 and 0.857, respectively. The test-retest reliability of the sub- and total scores of the Y-SBT yielded an ICC of 0.82 (95% CI 0.74 - 0.87) and 0.89 (95% CI 0.84 - 0.93), respectively. The divergent validity for sub- and total-scores of the Y-SBT based on Quadruple Visual Analogue Scale score for on-going pain was r = 0.374 (p = 0.001) and r = 0.432 (p = 0.001), respectively. The Y-SBT had no ceiling or floor effects.Metal-organic framework (MOF) nanomaterials offer a wide range of promising applications due to their unique properties, including open micro- and mesopores and richness of functionalization. Herein, a facile synthesis via a solvothermal method was successfully employed to prepare amine-functionalized Cu-MOF nanospheres. Moreover, the growth and the morphology of the nanospheres were optimized by the addition of PVP and TEA. By functionalization with an amine group, the immobilization of a bioreceptor towards the detection of hepatitis B infection biomarker, i.e., hepatitis B surface antigen (HBsAg), could be realized. The immobilization of the bioreceptor/antibody to Cu-MOF nanospheres was achieved through a covalent interaction between the carboxyl group of the antibodies and the amino-functional ligand in Cu-MOF via EDC/NHS coupling. The amine-functionalized Cu-MOF nanospheres act not only as a nanocarrier for antibody immobilization, but also as an electroactive material to generate the electrochemical signal. The electrochemical sensing performance was characterized using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and differential pulse voltammetry (DPV). The results showed that the current response proportionally decreased with the increase of HBsAg concentration. More importantly, the sensing performance of the amine-functionalized Cu-MOF nanospheres towards HBsAg detection was found to be consistent in real human serum media. This strategy successfully resulted in wide linear range detection of HBsAg from 1 ng mL-1 to 500 ng mL-1 with a limit of detection (LOD) of 730 pg mL-1. Thus, our approach provides a facile and low-cost synthesis process of an electrochemical immunosensor and paves the way to potentially utilize MOF-based nanomaterials for clinical use.Although it has been extensively studied for decades, the α-Al2O3Cr3+ phosphor has rarely been investigated for horticultural lighting. In this work, for the first time, a prototype of a plant growth light-emitting diode (LED) has been fabricated by coating a deep-red-emitting α-Al2O3Cr3+ phosphor onto a near-ultraviolet (NUV) chip. The α-Al2O3Cr3+ phosphor, synthesized by a co-precipitation method and annealed at 1500 °C for 2 h, emits an outstanding narrow peak at 695 nm. The α-Al2O30.6%Cr3+ phosphor shows a high activation energy of 0.29 eV, a long lifetime of 3.4 ms, and a superior color purity of 100%. The chromatic coordinates and the QE value of the red LED obtained by coating an α-Al2O30.6%Cr3+ phosphor on a NUV chip are (x = 0.5650, y = 0.2429) and 87.1%, respectively.This paper presents a new method of generating property-energy consistent (PEC) basis sets that can be applied to any arbitrary molecular property. The PEC method generates a basis set that is optimized for the molecular property under interest, providing the least possible total molecular energy. The main algorithm of the PEC approach involves Monte Carlo simulations to generate random exponents in the predetermined range. In this work, the PEC method is introduced in the example of generation of new pecJ-n (n = 1, 2) basis sets suited for high-quality correlated calculations of indirect nuclear spin-spin coupling constants involving the most popular NMR-active nuclei 1H, 13C, 15N, and 19F.The evolution of cost-effective hydrogen evolution reaction (HER) electrocatalysts is of great significance for the development of clean energy. https://www.selleckchem.com/products/salinosporamide-a-npi-0052-marizomib.html Exploring effective synthesis strategies to optimize the performance of non-noble metal electrocatalysts has always attracted our attention. Herein, ultrathin coordination polymers were used as precursors to controllably synthesize two-dimensional (2D) ultrathin dual-phase transition metal selenide (TMSs)/carbon-nitrogen (CN) composites (CoSe2-NiSe2/CN) by a two-step method (first a low temperature hydrothermal method for selenization, and then high temperature calcination selenization). Benefiting from its large specific surface area (49 m2 g-1), abundant catalytically active sites and synergistic effects, CoSe2-NiSe2/CN can significantly enhance the HER catalytic activity and exhibits good electrocatalytic activity with an overpotential of 150 mV at -10 mA cm-2, and a small Tafel slope of 42 mV dec-1 in an acidic electrolyte for the HER. This work provides a new strategy for optimizing the HER catalytic activity of TMSs by preparing 2D ultrathin dual-phase TMS composite materials.We have explored the structural and energetic properties of OC-BX3 (X = F, Cl, or Br) complexes using computations and low-temperature infrared spectroscopy. Quantum-chemical calculations have provided equilibrium structures, binding energies, vibrational frequencies, and B-C potential energy curves. The OC-BF3 system is a weak, long-bonded complex with a single minimum on the B-C potential (R(B-C) = 2.865 Å). For the remaining two complexes, OC-BCl3 and OC-BBr3, computations predict two stable minima on their B-C potential curves. The BCl3 system is a weak complex with a long bond (R(B-C) = 3.358 Å), but it exhibits a secondary, meta-stable minimum with a short bond length of 1.659 Å. For OC-BBr3, the system is a weak complex with a relatively short bond of 1.604 Å (according to wB97X-D/aug-cc-pVTZ), but also has a secondary minimum at R(B-C) = 3.483 Å. This long-bond structure is the global minimum according to CCSD/aug-cc-pVTZ. In addition, the long-bond forms of both OC-BCl3 and OC-BBr3 were observed in matrix-isolation IR experiments.